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I bought used psu power supply without main 24 pin cable and after bought 24 pin cable from AliExpress. I didn't find suitable cable for that psu, and buy cable for Corsair. On all internet looked and I can`t find that psu pin-out. First I looked inside psu, and with multimeter from PCB to pins search and write pin-out table, and rewire my cable from AliExpress. For you "Thermaltake thoughtpower  grand 850 W power supply pin-out".